You can run 'bleachbit', delete archived log files, possibly clean the package cache, and, as mentioned above, search for large files. The /usr directory is usually the largest, but /var usually has more you can delete. Given the size of '/', I would say there is some wasted space.
On my lappy I have a 1tb ssd, and I'm not careful at all about how much is stored in '/'. I never clean it out. and it's got about 19GB in it. Also have a look at /home/user/.xsession-errors.
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