No... sit0 is nothing to do with WiFi.
sit0 is to do with IPv6 and tunnels (in this case it looks like it's tunnelling IPv6 connections through your IPv4 setup)
WiFi cards will identify themselves as wlan0, wlan1 etc
lo is the loopback interface.
Ethernet (nic) cards will be eth0, eth1 etc. I suspect the second interface you are looking for is called eth1.
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