Suspecting two problems.
1. Check sendmail is listening only on localhost ??
netstat -an
if it is listening only on localhost then remove Addr part in the sendmail.cf file
O DaemonPortOptions=Port=smtp,Addr=127.0.0.1, Name=MTA
The line should be like this.
O DaemonPortOptions=Port=smtp Name=MTA
Enable relay for the respective client IP address.
Second problem:
In mail2web u are able to send mails not able to receive mails.
check imap and po3 is installed and enabled..
netstat -an
Siddiqu.T