What network client package are you using? Wicd, wpa_supplicant? Are you using a front end? What kind if security does your network have? I have wpa2 so I use wpa_supplicant. Chroot into your environment and emerge iw so you can run this commands. There's good documentation at
www.gentoo.org like the handbook and the gentoo wikis have good docs too. But in the meantime start dhcpcd and if you didn't symllink net.lo that could very well be your problem. Everyone forgets to do that. If you have IRC I highly suggest going in the #gentoo channel in irc.freenode.net for help too. That's where I'm always at including the gentoo developers.
-cmj