You can just use ifconfig and append a colon and a number (eth0:0) or nickname (eth0:test) to the device name, for example:
[root@dhcppc0 root]# ifconfig eth0:test 192.168.0.175 broadcast 192.168.0.255 netmask 255.255.255.0 up
I'm not sure of the distro-specific ways to permanently save this, though.
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