if you want to keep your windows server but change all linux client(using winbind),then go to:-
http://ubuntuforums.org/archive/index.php/t-91510.html
if you want to setup entire linux network, u can use openldap+ssl+redhat/centos as server. Client PC using ubuntu, suse, mandriva or etc.
In enterprise environment I would recommend suse 10.1 as client, because you can centralize authentication easily (event laptop user able to authenticate offline). The password policy can remain, after user login they will get immediately prompt for changing the password (just like windows under AD environment). However the performance is little bit slow (Slow but stable, not like windows always lightning at begining but ninja turltle finaly).
However, I won't recomment you to start right now because your organization may not ready. Please try to migrade all your client pc's IE to firefox (or opera), MS Office to OOffice. Photoshop to gimp. Outlook express to Thunderbird or etc.
Remember open source is cool, but not meaning suitable to everybody, in enterprise environment you must have a test, test, and test. Linux is only the OS, the most important portion is the application. I am having many problem on openoffice in my company because of compatiblity issue.
Is it answer your question?
Regards,
Ks