I've used both ATI (Radeon 9700) and Nvidia (FX 5500) cards, and at least in my experience, on a scale from one (easiest) to ten (hardest), the driver installation process for Nvidia was maybe a 2, while the ATI process was maybe a 9. YMMV, and I was not using Fedora so I cannot comment on how well it supports this card.
I'd suggest searching LQ for more threads about the ATI and Nvidia driver installation process -- it may be useful in giving you a better picture about what others folks' experiences have been. In any case, good luck with the upgrade, whichever decision you make -- J.W.
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