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Originally posted by idamlaj
Which distribution and development environment would be best, considering that students will have to learn how to use linux?
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For beginners text editor+command line to compile and run programs. For more advanced users (who know what Makefiles, autoconf and such things are - or for beginners who don't need to know) environment right for the language they use. I recommend KDevelop, but Anjuta is also good and simplier, so it may be a better choice for the first time. You can have both installed, so people can later choose.
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How would the computers need to be set up in order to connect through OS X samba-enabled shares?
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It depends what you mean by that. When the machines will be clients only, no special setup is needed.
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Are samba volumes mountable from the gui while being a non-root user?
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Yes. KDE for example has 'Mount' and 'Unmount' options in right-click menu.
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Are samba volumes unmounted upon logout?
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By default I think they aren't. But it's possible to set up script at logout to do this.
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What about printers on the network? Will it be easy to set linux up to print on these?
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Printers need to be configured, but it shouldn't be hard.