Theres a lot written for both, It depends on what your aiming for with your software. Plus stuff thats written for CLI, usually ends up being backends for X Windows stuff.
Take K3b probably the best burning program, but it actually uses cdrecord cdrdao and others to do the actual burning.
If you like CLI programming *nix's in general are a good platform to do it on, its much more likely to be used.
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