What you wanna do it's quite easy. Just follow these steps:
- create a file named ifcfg-eth0:1 in your /etc/sysconfig/network-scripts directory;
- write this in that file:
DEVICE=eth0:1
ONBOOT=yes
BOOTPROTO=static
# here you should make some adjustments
IPADDR=192.168.1.1
# here too
NETMASK=255.255.255.224
# and here
GATEWAY=192.168.1.1
- restart your network service
Ok, you're up and runnin'...
Good luck.