Code:
ifconfig eth0:2 192.168.0.1 netmask 255.255.255.0 broadcast 192.168.0.255 up
ifconfig eth0:3 192.168.12.1 netmask 255.255.255.0 broadcast 192.168.12.255 up
ifconfig eth0:254 10.0.0.1 netmask 255.0.0.0 broadcast 10.255.255.255 up
i am sure you can get the idea from that.
if you want them to be permanent (persist through reboots, network service restarts, etc) you can create the file with appropriate information
located in /etc/sysconfig/network-scripts
to get a start use the ifcfg-eth0 file. cp ifcfg-eth0 ifcfg-eth0:1 and then edit it appropriately being sure to change
DEVICE=eth0 to
DEVICE=eth0:1
hope this helps