try to put the file location into "" it contains spaces and mplayer (and all linux commands) treats spaces as command line arguments separation, to avoid it you can either escape spaces with \ or use double quotes
P.S. and to instruct mplayer to play certain video files you must compile it with the appropriate support for these types of files there are mplayer codecs available at the motehr site of mplayer (
http://www.mplayerhq.hu ) you can extrac them into /usr/lib/win32 and during mplayer ./configure step first run
./configure --help
to see what is available for you - it is quite a lot, so you might want to pipe the output to less/more)