a few problems CentOS dose NOT backport or support older minor versions ( like red hat dose)
Centos 5.3 and 5.4 are unsupported
CentOS 5.5 uses kde 3.5 and QT 3
all the rpm's are in the MAIN repos !
the easiest way ( if only Gnome is installed ) is to install kde and the kde devel tools ( "add and remove software" GUI or use yum )
cent 5 USES QT3 !!!!
if you NEED QT4.4 ???? have fun - or install a different OS
now there IS a "experimental" centOS repo for installing KDE 4 and qt4 ON CENT 5.5 --- but use at your own risk
you might want to read the CentOS wiki
http://wiki.centos.org/