I have the same problem!
I have exactly the same problem as you, and whenever I try to remove profiles aMSN tells me they are being used too, I even tried removing all the profiles manually, but when I start the program one of the profiles appears! this is odd...
I think there must be a profile lock or something somewhere around .amsn directory, but I can't find anything...
Anyways, if you figure out how to solve this please let me know...
Thanks!
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