Are you trying to join a workstation to the domain or adding the PDC to an existing workgroup?
To allow you to add workstations users and groups, you also will need the following in your smb.conf
add user script = /usr/sbin/useradd -m %u
delete user script = /usr/sbin/userdel -r %u
add group script = /usr/sbin/groupadd %g
delete group script = /usr/sbin/groupdel %g
add user to group script = /usr/sbin/groupmod -A %u %g
delete user from group script = /usr/sbin/groupmod -R %u %g
add machine script = /usr/sbin/useradd -s /bin/false -d /var/lib/nobody %u
Check out the Samba guide at
http://www.samba.org/samba/docs/man/...TO-Collection/
Regards