What you want to do is not too difficult a task. You should first plan your installation and RAID configuration. Now that you want RAID 1, you can see here
http://www.firstpr.com.au/web-mail/CentOS-5.1-RAID-1/ assuming that you are looking at software raid and not the hardware part. If it is a hardware raid, procedure is going to be different entirely. And possibly you can configure raid at installation. It will save you time later.
THIS LINK will help you with samba configuration.
You need to have a backup at any cost if your server is a production server. There is a saying, he who had a last laugh probably has backups. There are a lot of options for backup. You will need to decide on yourself how big your backups are going to grow and what you want and how important the data is going to be.
RSYNC is one of the best for backups even incremental as well. There are GUI front end tools for rsync if you are not familiar with it.
There are other backup softwares like
Amanda,
Bacula among others.
You can have a image of your installation as well. You can use
CloneZilla for the same.