sync
should be performed by the shutdown scripts. It won't hurt anything if you issue it yourself. I bind a key sequence to a suspend script that calls sync twice - just in case
Depending on the file system you use, and options you may have specified, they sync at different intervals. ext3/4 by default syncs every 5 seconds.
Quote:
Originally Posted by man mount
commit=nrsec
Sync all data and metadata every nrsec seconds. The default value is 5 seconds. Zero means default.
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Consult the various man pages, or have a look here
http://www.kernel.org/doc/Documentation/filesystems/