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You cannot burn DVDs with mkisofs, because as its name suggests it makes .iso files. It doesn't burn anything. 'growisofs' is the best program for burning DVDs, you could technically also use 'cdrecord' but the feature was only added recently, and it probably has less features. I'm sure there's a package for it, I believe it is dvd+-rw-tools or something similar. So use yum to install it.
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