Compiling and installing the xine to work from the source tarball is too much hectic for a newbie. Try downloading the RPMs from www.qualityrpms.siteburg.com
and follow the instructions mentions there. I can guarantee that these RPMs will work. There are two UI RPMs also there, the official Xine-UI and Gxine. Try to download and install these RPMs for the UIs that you want. HAPPY WATCHING WITH XINE VIDEO PLAYER.