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if the filesystem if vfat or ntfs...
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Ah! You've hit the nail on the head - I kick myself now for not realising before.
The text files affected are on the NTFS partition of my hard drive, because I also access them through Windows (it's a dual boot machine). If I create an sample text file on my ext3 partition, there is no problem changing that setting.
Thank you for clearing up my query.