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Format the drive with either Reiserfs or Ext3. Since you are sharing with Windows computers, Samba will need to be installed. Samba will allow access to the Ext3/ReiserFS filesystems, so Please don't use FAT32.
You could mount the hard drive under /home assuming that /home is empty. If there are files/folders under /home, you'll need to move them to the second hard drive before mounting it as /home.
I didn't read that you are sharing these files with other linux computers, but if you are, look into NFS for sharing between linux PCs
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