Hopefully, this will be pretty easy. Here's what, from what I understand from your setup (Forward from one NIC to the other NIC), you need to do.
You need to open up ports 110 for POP3 and 25 for SMTP in your firewall. Next, you'll need to configure your gateway to forward port 110 and port 25 to 192.168.x.x, I assume you'll be using a statically assigned address for the device you forward these to.
Also, if I understand what you're saying correctly, you'll want to enable TCP/IP forwarding (There should be tutorials for this out there, I don't know how to myself.) so that it'll allow you access from outside the LAN.
I hope this will help get you started.
