I'm pretty sure LVM doesn't work across a network. There are a number of parallel filesystem available such as PVFS and Lustre. Also, the next revision of the NFSv4 spec will include a way to do parallel NFS. However, all of these are fairly new and/or experimental, and thus not for the faint of heart. Plus I'm not sure how well it works with Windows (and I'm not sure if SAMBA implements Microsoft's Distributed File System stuff) If you're willing to spend a lot of money there is commercial solutions from folks like EMC. Normally I would say those things are beyond a home user's grasp, but given that you have 7 TB of home storage, I might be wrong

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