Which program are you trying to run??? They're installed in lots of different locations.
If you're at a command line, try:
rpm -ql <package name> such as rpm -ql gqview
This will throw out a large list of whatever files are in that RPM package, with their paths. Look at the lines, and you should see some in /bin, /usr/bin, /sbin/, etc. One will probably be what you need.
If you're using KDE, it'll probably shove it into your menus somewhere. I don't use Gnome, but it probably will put it in there, too.
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