If by 'SSD caching' you mean 'Smart Response Technology' (SRT), then no, you cannot use it with linux. Its proprietary, there is no linux support, its windows only.
BTW, ICH10 isnt the requriement for SRT. You need a Z68 (or newer) chipset.
There are linux native SSD caching projects, like bcache-
While I've never used bcache, dont expect bcache to perfrom the same as SRT does, e.g., as far as I know bache will have very little effect on boot times.