I'm assuming you want these to be separate from your existing RAID1, sort of mirrored on their own? If so..
You'll want to create a new partition (6) in your case (on both drives).
Code:
# parted /dev/sda
(parted) mkpart logical 3184Gib 4001Gib
(parted) set 6 raid on
(parted) align-check optimal 6
After you created your partition 6 on each drive device, you need to create an MD device and then add them to be mirrored:
Code:
# mdadm --create /dev/mdX --level=1 --raid-devices=2 /dev/sda6 /dev/sdb6
Where X in /dev/mdX is your new unused md device (some start at 0, some start at 126 or 127, just make sure to use one you aren't already using for the existing RAID1 setup). Get the existing ones by doing a:
Once you get your RAID1 going, you can format the device with whatever filesystem you prefer (ex. mkfs.ext4 /dev/mdX). Once it has a filesystem, you can mount it to start using it. (Also add to /etc/fstab to mount at boot time of course).
I'm also assuming the new partitions are devices sda6 and sdb6, you'll want to do an fdisk -l to make sure.
I'm doing most of this from memory so you might want to double check my commands. Always backup your data before doing these types of changes as well.
But those should be the basic steps in adding your unused disk space in it's own RAID1 mirror.