I think that most of that will be the same. the file /etc/passwd stores uid and all that.... here's a clip from mine:
adam:x:1001:100::/home/adam:/bin/bash
that's username, x means there's a password, UID, GID, home dir, login shell
and group definitions are in /etc/group this is from the man page:
group_name
asswd:GID:user_list
If you're using the same shell, then .profile should stay the same.
I was thinking about this today.... I think everything will be cool except for the passwords. You might need to to go through and set each user's password from root (maybe you could make a bash script to do that for you), and then have all of the users login and set a new password.
you might even want to make a backup of everything in /etc so that you can look info up if needed.
... just my thoughts on the subject....
good luck