I'm not sure if you're asking about this, but...
in KDE i use:
Win+W=xmms (like WinAmp)
Win+R=console (like Windows->Run)
Win+E=konqueror (like Explorer)
F2=save a file in KWrite

F3=search a file in konqueror (like IE again)
And about X. You can run 7 Xs simultaneously and switch thru Ctrl+Alt+F(7-12). Just "startx -- :1" for F8, "startx -- :2" for F9... but it's unconvinient to have several Xs.