I'm not quite sure what you think you mean by mirroring..
However, the /boot for Linux can only be on RAID1 (aka mirror)
http://en.wikipedia.org/wiki/RAID#Standard_levels if you want to raid it.
RAID basically gives you ways of making more resilient disksets that look like 1 disk to the filesystem.
LVM2
http://en.wikipedia.org/wiki/LVM2,
http://sourceware.org/lvm2/ allows you to group multiple disks into one large diskset (aka volumegroup) that you can then split arbitrarily into Logical Volumes and then put a filesystem on top of each LV.
These 2 are not the same thing.
Note that you can RAID disks together, then put LVM on top, then split into LVs and put filesystems on top.
Your choice.
I suggest you have a good read and then come back with a design.