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For one thing, partitions must consist of contiguous space on the drive (they can't be fragmented). You would only be able to "trade" space if the two partitions were physically adjacent to each other. Another problem is that some repartitioning programs (e.g. GNU Parted) will "grow" a partition upward/outward, but will not allow you to alter the partition's start point, which is what needs to be done in your case. Check out Partition Magic; it isn't free, but it will probably do the trick.
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