If your only running one DE at a time it shouldn't conflict with the other.
However if you have dual monitors one running KDE and one running Gnome it might but I think that's not so much a problem like it used to be in 2008 and earlier.
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Would a simplified solution be to dual boot?
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You would only dual boot if you already have one os installed on your current drive and wish to install another os on that same drive.-
-::-When you boot your os your should have the option to choose between Gnome and KDE Plasma.-::-