Thanks for the reply, but later in the day I answered my own question. This is what I said and did.
Duh!! I can mount the Samba share and load the playlist via xmms.
#mkdir /mnt/mntpoint
#mount -t smbfs -o username=username,password=password //windowssystem/shares /mnt/mntpoint
$xmms&
Then load playlist... Listening Pleasure commence!!
P.S. If I am not mistaken, if no username or password is required "defaults" can be used as placeholders. IE: username=defaults,password=defaults
I will have to try "defaults" later.