GNOME isn't a bootloader, it's a desktop environment. I think you mean GRUB. Really, you could have found the answers to your questions in the GRUB manual, but I'll answer them anyway. You need to edit your /boot/grub.conf or /boot/menu.lst to make the changes.
1. Look for the line that says "timeout x", where x is the number of seconds before booting the default entry. Change it to whatever you want.
2. Look for the line that says "default x", where x is the number of the entry that is the default (starting from 0, so the second entry would be 1). Change it to the relevant number.
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